Azulene based metal-organic frameworks for strong adsorption of H2.

نویسندگان

  • Samir Barman
  • Hiroyasu Furukawa
  • Olivier Blacque
  • Koushik Venkatesan
  • Omar M Yaghi
  • Heinz Berke
چکیده

Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H(2) interactions (7.8-6.8 kJ mol(-1)), which revealed the significant impact of internally polarized azulene backbone to stabilized H(2) molecules in the framework.

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عنوان ژورنال:
  • Chemical communications

دوره 46 42  شماره 

صفحات  -

تاریخ انتشار 2010